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2025, 11, v.44 7-11
高耐蚀镀金层的制备工艺及性能
基金项目(Foundation):
邮箱(Email):
DOI: 10.19289/j.1004-227x.2025.11.002
摘要:

[目的]为解决锌合金压铸件氰化物镀金污染严重、整体耐蚀性不足等问题,开发一种高耐蚀镀金新工艺。[方法]对锌合金基体依次进行无氰镀铜锌合金、焦磷酸盐镀铜、镀酸铜、镀光亮镍、镀镍锡合金和镀冲击金。[结果]本工艺在高防腐镍锡合金镀层上镀冲击金,镀层间结合良好,经热震试验无起泡或脱落,中性盐雾试验240 h无锈蚀。[结论]该工艺绿色环保,镀层性能优异,成本较低,具有良好的应用前景和市场推广价值。

Abstract:

[Objective] A novel gold plating process for preparing highly corrosion-resistant coating was developed, aiming to address the critical issues of cyanide-based gold plating on zinc alloy die castings, such as severe environmental pollution, and insufficient overall corrosion resistance. [Method] A multi-layered coating was prepared on zinc alloy substrate through a sequential process involving cyanide-free copper–zinc alloy plating, pyrophosphate copper plating, acid copper plating, bright nickel plating, nickel–tin alloy plating, and strike gold plating on the zinc alloy die casting. [Result] By applying the strike gold plating over the high corrosion-resistant nickel–tin alloy layer, excellent interlayer adhesion was achieved. The obtained coating passed the thermal shock test without blistering or peeling, and withstood 240-hour neutral salt spray test without any signs of corrosion. [Conclusion] The newly developed process is environmentally friendly, can prepared coatings with superior performance at a relatively lower cost, demonstrating promising application prospects and significant market potential.

参考文献

[1]杨家强,金磊,杨防祖,等.无氰镀金进展概述[J].电镀与精饰, 2019,41(12):35-43.YANG J Q, JIN L, YANG F Z, et al. Overview of cyanide-free gold plating progresses[J]. Plating&Finishing, 2019, 41(12):35-43.

[2]秦足足,李建三,徐金来.国内外无氰镀铜工艺研究进展[J].电镀与涂饰, 2015, 34(3):149-152.QIN Z Z, LI J S, XU J L. Research progress of cyanide-free copper electroplating at home and abroad[J]. Electroplating&Finishing, 2015,34(3):149-152.

[3]马涛,李运刚,杨桂宇,等.钢铁基体无氰镀铜工艺研究现状[J].铸造技术, 2016, 37(12):2579-2582.MA T, LI Y G, YANG J Y, et al. Research progress on non-cyanide copper plating of steel matrix[J]. Foundry Technology, 2016, 37(12):2579-2582.

[4]广州超邦化工有限公司.一种聚硫氰酸盐镀银层:202320151949.6[P]. 2023–12–19.LI X H, GUO C W, LAI H W, et al. A silver coating plated from polythiocyanate-bsed bath:CN220202061U[P]. 2023–12–19.

[5]广州超邦化工有限公司.一种航空航天钛合金零部件无氰镀镉铁合金工艺:202411962347.4[P]. 2025–03–25.GUO C W, WANG D M, LI X H, et al. A cyanide-free cadmium–iron alloy plating process for aerospace titanium alloy parts:CN119685893A[P]. 2025–03–25.

[6]烟台南山学院.一种锌合金压铸件无氰镀镉铁合金工艺:202411789059.3[P]. 2025–04–08.ZHOU Y C, GUO C W, ZHANG Q, et al. A cyanide-free cadmium–iron alloy plating process for zinc alloy die casting:CN119663389A[P].2025–04–08.

[7]广州超邦化工有限公司.一种无氰铜锌合金镀液及电镀工艺:202411436681.6[P]. 2025–01–03.GUO C W, LI X Y, CHEN M, et al. A cyanide-free copper–zinc alloy plating bath and electroplating process:CN119243274A[P]. 2025–01–03.

[8]广州超邦化工有限公司.一种铝合金件以无氰镀铜锌合金作底镀层的镀锌镍合金工艺:202411269963.1[P]. 2024–11–19.GUO C W, LI X H, LI X Y, et al. A zinc–nickel alloy plating process for aluminum alloy part pre-plated with cyanide-free copper–zinc alloy:202411269963.1[P]. 2024–11–19.

[9]广州超邦化工有限公司.一种航空航天合金钢锻造机加件的无氰镀镉方法:202411436667.6[P]. 2025–03–21.GUO C W, ZHOU Z Y, LI X H, et al. A cyanide-free cadmium plating process for aerospace alloy steel forged machined components:202411436667.6[P]. 2025–03–21.

[10]广州超邦化工有限公司.一种镁合金无氰镀镉铁合金工艺:202411779601.7[P]. 2025–02–21.GUO C W, LI X Y, CHEN M, et al. A cyanide-free cadmium–iron plating process of magnesium alloy:CN119491277A[P]. 2025–02–21.

[11]广州超邦化工有限公司.一种钕铁硼永磁体镀镍工艺:202411270163.1[P]. 2024–12–06.GUO C W, LI X H, LO X P, et al. A nickel plating process for NdFeB permanent magnet:CN119082817A[P]. 2024–12–06.

[12]广州超邦化工有限公司.一种适用于航空航天领域的钕铁硼无氰镀镉铁合金工艺:202411779098.5[P]. 2025–03–11.GUO C W, LI X H, LAI H W, et al. A nickel plating process for NdFeB permanent magnet:CN119592937A[P]. 2025–03–11.

[13]陈康,郭崇武,彭超艺,等.以镀锌镍合金和化学镀镍作底层的锌合金压铸件镀金工艺[J].电镀与涂饰, 2020, 39(11):701-702.CHEN K, GUO C W, PENG C Y, et al. Process for gold plating on zinc alloy die castings pre-plated with zinc–nickel alloy coating and electroless nickel coating[J]. Electroplating&Finishing, 2020, 39(11):701-702.

[14]广州超邦化工有限公司.一种闪镀金镍合金的镀层结构:202323593540.9[P]. 2024–09–20.GUO C W, LAI H W, PENG C Y, et al. The coating structure of a flash gold-plated nickel alloy:CN221740480U[P]. 2024–09–20.

[15]宋振兴,马树元,姚素薇等.电镀镍-锡合金耐腐蚀性能研究[J].电镀与精饰, 2013, 35(10):1-4, 16.SONG Z X, MA S Y, YAO S H, et al. Corrosion of resistance of electroplating Ni–Sn alloy[J]. Plating&Finishing, 2013, 35(10):1-4, 16.

[16]冯绍彬,商士波,包祥,等.电位活化现象与金属电沉积初始过程的研究[J].物理化学学报, 2005, 21(5):463-467.FENG S B, SHANG S B, BAO X, et al. Study of potential activation phenomenon and initial process of metal electrodeposition[J]. Acta Physico-Chimica Sinica, 2005, 21(5):463-467.

[17]冯绍彬,胡芳红.“电位活化”现象与无氰直接镀铜[J].电镀与涂饰,2008, 27(3):4-6, 11.FENG S B, HU F H. Potential activation phenomenon and non-cyanide direct copper plating[J]. Electroplating&Finishing, 2008, 27(3):4-6, 11.

[18]郭崇武,易胜飞.钢铁件直接焦磷酸盐镀铜工艺研究[J].电镀与精饰, 2009, 31(8):11-14.GUO C W, YI S F, Investigation on direct copper plating technology of steel workpieces in pyrophosphate bath[J]. Plating&Finishing, 2009,31(8):11-14.

基本信息:

DOI:10.19289/j.1004-227x.2025.11.002

中图分类号:TG174.4

引用信息:

[1]郭崇武,李小花,王晓军.高耐蚀镀金层的制备工艺及性能[J].电镀与涂饰,2025,44(11):7-11.DOI:10.19289/j.1004-227x.2025.11.002.

基金信息:

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