电镀与涂饰

2025 04 v.44 30-38

Si_3N_4含量对Ni–P–WS2–Si_3N_4复合化学镀层在不同温度下摩擦磨损性能的影响

唐建平;黄寅迪;林锋;袁严浩瀚;王军平;郑晓华;

基金项目(Foundation):

邮箱(Email):

DOI: 10.19289/j.1004-227x.2025.04.005

中文作者单位:

杭州杭氧锻热有限公司;浙江晶越半导体有限公司;浙江工业大学材料科学与工程学院;浙江省机电产品质量检测所有限公司;

摘要(Abstract):

[目的]Ni–P–WS_2化学镀层具有良好的润滑性能，但其耐磨性不足，难以满足高温、重载等苛刻工况需求。[方法]通过在Ni–P–WS_2复合镀液中添加Si_3N_4纳米颗粒，化学镀得到Ni–P–WS_2–Si_3N_4复合镀层，并进行400℃退火处理。利用扫描电镜(SEM)、X射线衍射仪(XRD)和摩擦磨损试验机分析了镀层的组织结构及其在不同温度下的摩擦学特性。[结果]随着镀液中Si_3N_4用量增加，Ni–P–WS_2–Si_3N_4复合镀层表面呈现致密化趋势，在4.0 g/L时镀层的Si_3N_4含量、硬度和平均摩擦因数达到峰值，而磨损率在所有测试温度下均单调下降。随试验温度升高，Ni–P–WS_2–Si_3N_4复合镀层的磨损机制由室温下的粘着磨损转变为高温下的磨粒磨损。Si_3N_4的加入显著提升了镀层的高温稳定性，在600℃时仍未出现磨穿现象。[结论]Si_3N_4用量为4.0～5.0g/L时，退火态Ni–P–WS_2–Si_3N_4复合镀层在25～400℃范围内均展现出优异的摩擦学性能，其耐磨性为Ni–P–WS_2复合镀层的5倍以上，适用于高温、重载等服役环境。

关键词(KeyWords): 化学镀;镍-磷合金;氮化硅;二硫化钨;摩擦学性能;热处理

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基本信息:

DOI：10.19289/j.1004-227x.2025.04.005

中图分类号:TQ153;TH117.1

引用信息:

[1]唐建平,黄寅迪,林锋等.Si_3N_4含量对Ni–P–WS2–Si_3N_4复合化学镀层在不同温度下摩擦磨损性能的影响[J].电镀与涂饰,2025,44(04):30-38.DOI:10.19289/j.1004-227x.2025.04.005.

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