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2025 04 v.44 24-29
一种新型水下固化高性能防腐涂料的制备与性能研究
基金项目(Foundation): 国家重点研发计划“海洋建筑结构用耐蚀钢及防护技术”(2021YFB3701700)
邮箱(Email):
DOI: 10.19289/j.1004-227x.2025.04.004
中文作者单位:

广东腐蚀科学与技术创新研究院;广东粤海粤西供水有限公司;

摘要(Abstract):

[目的]采用双酚A环氧树脂和改性胺固化剂为基体材料,辅以玻璃鳞片等无机填料,开发出了可在潮湿表面及水下施工固化的涂料。[方法]通过圆柱弯曲试验、铅笔硬度试验、抗冲击试验及附着力试验,考察了涂层的力学性能。通过电化学阻抗谱和中性盐雾试验,分析了该涂料在水下固化环境中对钢铁基材的防护性能。[结果]涂布在316钢板上的涂层样品于水下固化后的拉拔附着力可达4.64 MPa,在3.5%NaCl溶液中浸泡100 d后其低频阻抗模值与浸泡初期仍保持在同一数量级,中性盐雾腐蚀3 000 h后涂层表面无起泡、生锈现象,拉拔附着力为1.89 MPa,划痕腐蚀宽度为9.05 mm。[结论]本研究制备的涂料具有优异的防腐性能,可以有效修复海工装备,延长其服役寿命。

关键词(KeyWords): 海工装备;防腐;修复;低表面处理涂料;水下固化
参考文献

[1]张宏辉.石墨烯改性水下施工固化无溶剂环氧防腐蚀涂料的研制[J].涂料工业, 2019, 49(6):11-14.ZHANG H. Development of graphene-modified underwater curing solvent-free epoxy anticorrosive coatings[J]. Paint&Coatings Industry,2019, 49(6):11-14.

[2]黄从树.水下修复防腐涂料用环氧树脂改性研究[J].材料开发与应用, 2017, 32(2):68-73.HUANG C S. Study on the modification of epoxy resin used in underwater repairing anticorrosive coatings[J]. Development and Application of Materials, 2017, 32(2):68-73.

[3]凌芹,程皓然,郭思,等.高固体分水下固化重防腐涂料的制备与应用研究[J].中国涂料, 2021, 36(8):11-14.LING Q, CHENG H R, GUO S, et al. Preparation of high solids underwater curing heavy-duty anticorrosive coatings and research on application[J]. China Coatings, 2021, 36(8):11-14.

[4]闫兴艳,彭阳峰,童天中,等.潮湿表面用环氧树脂固化剂的合成及其性能[J].热固性树脂, 2022, 37(5):1-6.YAN X Y, PENG Y F, TONG T Z. Synthesis and properties of epoxy resin curing agent for wet surface[J]. Thermosetting Resin, 2022,37(5):1-6.

[5] GU Y J, YANG J H, ZHOU S X. A facile immersion-curing approach to surface-tailored poly(vinyl alcohol)/silica underwater superoleophobic coatings with improved transparency and robustness[J]. Journal of Materials Chemistry A, 2017, 5(22):10866-10875.

[6] SETHIYA A, JANGID D K, PRADHAN J, et al. Role of cyanuric chloride in organic synthesis:a concise overview[J]. Journal of Heterocyclic Chemistry, 2023, 60(9):1495-1516.

[7]曾志文,张夏虹.潮湿固化环氧化学灌浆材料的研制[J].水运工程,2010(10):19-22.ZENG Z W, ZHANG X H. Research on moisture curable epoxy chemical grouting material[J]. Port&Waterway Engineering, 2010(10):19-22.

[8]朱华,张晓华,陈晓龙.水下环氧树脂胶粘剂用水下固化剂的性能研究[J].中国胶粘剂, 2013, 22(4):17-20.ZHU H, ZHANG X H, CHEN X L. Performance study of underwater curing agent for underwater epoxy resin adhesive[J]. China Adhesives,2013, 22(4):17-20.

[9] DUAN J, WU W, WEI Z, et al. Synthesis of functional catechols as monomers of mussel-inspired biomimetic polymers[J]. Green Chemistry, 2018, 20(4):912-920.

[10] LI G M, WU Y P, CHEN Z T, et al. Biomimetic epoxy adhesive capable of large-scale preparation:From structural underwater bonding to hydrothermal durability[J]. Chemical Engineering Journal, 2022,431(Part 1):134011.

[11] ZHOU J J, WAN Y, LIU N, et al. Epoxy adhesive with high underwater adhesion and stability based on low viscosity modified Mannich bases[J].Journal of Applied Polymer Science, 2018, 135(3):45688.

[12] HE J M, XU W X, LIU H, et al. Preparation of a novel 2-amino benzothiazole loaded ZIF-8/layer double hydroxide composite and its application in anti-corrosion epoxy coatings[J]. Progress in Organic Coatings, 2023, 185:107927.

[13] HE J M, LI M, LI D X, et al. Fabrication of azobenzene non-covalent bonding grafting graphene composite and its application in weathering and corrosion resistant polyurethane coating[J]. Polymer Degradation and Stability, 2022, 206:110157.

[14] XU W X, LIU H, HE J M, et al. Fabrication of multifunction polyurethane with robust, self-healing and anti-corrosion performance based multiple dynamic bonds strategy[J]. Progress in Organic Coatings, 2024, 192:108513.

基本信息:

DOI:10.19289/j.1004-227x.2025.04.004

中图分类号:TQ637

引用信息:

[1]武安琪,高立业,李健康等.一种新型水下固化高性能防腐涂料的制备与性能研究[J].电镀与涂饰,2025,44(04):24-29.DOI:10.19289/j.1004-227x.2025.04.004.

基金信息:

国家重点研发计划“海洋建筑结构用耐蚀钢及防护技术”(2021YFB3701700)

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