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[目的]探讨碱性硅烷化处理对铝合金炊具表面陶瓷不粘涂层附着力的影响及其机理。[方法]以3003铝合金为基材，在含硅溶胶和甲基三甲氧基硅烷的溶液中进行硅烷化处理，测量其后喷涂的陶瓷不粘涂层的附着力，采用傅里叶变换红外光谱仪、扫描电镜和能谱仪研究其化学结构和表面形貌。[结果]碱性硅烷化可以在3003铝合金表面形成一层很薄的表面处理膜，它可以明显提高基材与陶瓷不粘涂层之间的结合力。[结论]基材与处理膜的界面生成了大量的Al─O─Si键，处理膜与陶瓷涂层的界面也生成了大量的Al─O─Si和Si─O─Si键，这些化学键的键合作用提高了陶瓷不粘涂层在3003铝基材上的附着力。
Abstract：[Objective] The effect of alkaline silanization as a pretreatment on the adhesion of ceramic nonstick coating on the surface of aluminum alloy cookware and the related mechanism were explored. [Method] Using 3003 aluminum alloy as the substrate, silanization was conducted in a solution containing silica sol and methyltrimethoxysilane. The adhesion of the subsequently sprayed ceramic nonstick coating was measured, and its chemical structure and surface morphology were examined by Fourier-transform infrared spectroscopy(FT-IR), scanning electron microscopy(SEM), and energy-dispersive spectroscopy(EDS). [Result] A thin pretreatment film was formed on the surface of 3003 aluminum alloy by alkaline silanization, which significantly improved the adhesion between the substrate and the ceramic nonstick coating. [Conclusion] A large number of Al─O─Si bonds are formed at the interface between the substrate and the pretreatment film, and numerous Al─O─Si and Si─O─Si bonds are generated at the interface between the pretreatment film and the ceramic coating. The adhesion of the ceramic nonstick coating on the 3003 aluminum substrate is enhanced by the bonding effect of these chemical bonds.
[1]白洋.中国明火炊具及保温类产品市场：严峻宏观经济冲击下，期待市场复苏[J].现代家电, 2023(2):54-57.BAI Y. Chinese open-flame cookware and thermal insulation products market:expecting the market to recover under the severe impact of macroeconomic conditions[J]. Modern Household Appliances, 2023(2):54-57.
[2]LIU S H, ULUGUN B, DEFLORIO W, et al. Development of durable and superhydrophobic nanodiamond coating on aluminum surfaces for improved hygiene of food contact surfaces[J]. Journal of Food Engineering, 2021, 298:110487.
[3]孙鹏,董劲,黄惠,等.水性炊具陶瓷涂料的制备与性能研究[J].涂料工业, 2023, 53(1):1-8.SUN P, DONG J, HUANG H, et al. Study on preparation and properties of waterborne ceramic coatings for cookware[J]. Paint&Coatings Industry, 2023, 53(1):1-8.
[4]ZHENG J, SUN B S, BERARDI D, et al. Perfluorooctanesulfonic acid and perfluorooctanoic acid promote migration of three-dimensional colorectal cancer spheroids[J]. Environmental Science&Technology,2023, 57(50):21016-21028.
[5]朱东,陈瑶.我国不粘涂料现状与发展趋势[J].涂层与防护, 2022,43(3):55-62.ZHU D, CHEN Y. Current situation and development of nonstick coatings industry in China[J]. Coating and Protection, 2022, 43(3):55-62.
[6]王萌.铝合金表面陶瓷涂层制备工艺研究[D].武汉:华中科技大学, 2015.WANG M. Study on preparation processes of ceramic coating on aluminum surface[D]. Wuhan:Huazhong University of Science and Technology, 2015.
[7]李经奇.铝合金表面硅烷化处理及膜层腐蚀行为研究[D].哈尔滨:哈尔滨工程大学, 2022.LI J Q. Investigation on silane treatment of aluminum alloy and corrosion behavior of film[D]. Harbin:Harbin Engineering University,2022.
[8]张家豪.改性二氧化硅超疏水粒子的制备及其对建筑外墙乳液耐沾污性的影响[D].哈尔滨:哈尔滨工程大学, 2017.ZHANG J H. Preparation of modified superhydrophobic particles of silicon dioxide and their effect on stain resistance of exterior wall emulsion coating[D]. Harbin:Harbin Engineering University, 2017.
[9]ZANDI-ZAND R, ERSHAD-LANGROUDI A, RAHIMI A. Silica based organic–inorganic hybrid nanocomposite coatings for corrosion protection[J]. Progress in Organic Coatings, 2005, 53(4):286-291.
[10]YONA A M C,ŽIGON J, DAHLE S, et al. Study of the adhesion of silicate-based coating formulations on a wood substrate[J]. Coatings,2021, 11(1):61.
[11]CAI S, ZHANG Y L, ZHANG H L, et al. Sol–gel preparation of hydrophobic silica antireflective coatings with low refractive index by base/acid two-step catalysis[J]. ACS Applied Materials&Interfaces,2014, 6(14):11470-11475.
[12]顾宏,张文兴.硅烷薄膜前处理车身面漆附着力问题的分析与解决[J].电镀与涂饰, 2023, 42(16):49-53.GU H, ZHANG W X. Analysis on poor adhesion of basecoat on car body pretreated by silane-based thin film process and countermeasures:a case study[J]. Electroplating&Finishing, 2023, 42(16):49-53.
[13]SURIANO R, CIAPPONI R, GRIFFINI G, et al. Fluorinated zirconiabased sol–gel hybrid coatings on polycarbonate with high durability and improved scratch resistance[J]. Surface&Coatings Technology,2017, 311:80-89.
[14]孙振东,杨颜宁,宋秋实,等. Q235钢表面双硅烷复合膜的制备与性能表征[J].电镀与涂饰, 2019, 38(15):802-807.SUN Z D, YANG Y N, SONG Q S, et al. Preparation of double silane composite film on Q235 steel and characterization of its properties[J].Electroplating&Finishing, 2019, 38(15):802-807.
[15]周游,周帅,周江鸿,等.硅烷化氧化石墨烯/有机硅复合涂层的制备及性能[J].电镀与涂饰, 2023, 42(16):63-70.ZHOU Y, ZHOU S, ZHOU J H, et al. Preparation and properties of silanized graphene oxide/silicone composite coating[J]. Electroplating&Finishing, 2023, 42(16):63-70.
基本信息:
DOI：10.19289/j.1004-227x.2026.01.002
中图分类号:TG174.4
引用信息:
[1]卢嘉华,林英杰.铝合金表面碱性硅烷化处理对陶瓷涂层附着力的影响及其机理研究[J].电镀与涂饰,2026,45(01):8-14.DOI:10.19289/j.1004-227x.2026.01.002.
基金信息: