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[目的]为解决传统达克罗涂料中六价铬的致癌风险、高温固化能耗高、摩擦因数偏大及需附加润滑涂层等问题,开发一种兼具优异耐腐蚀性能、低摩擦因数及良好环境相容性的单次涂装达克罗涂料。[方法]采用自制的硅烷水解预聚物作为成膜基料,以片状锌粉和铝粉作为防锈颜料,并引入石墨烯/多壁碳纳米管预分散浆料。在此基础上,结合低温固化技术添加聚四氟乙烯(PTFE)乳液,通过系统调控预分散工艺参数、固化温度及PTFE乳液的粒径与添加量,对所得涂层的综合性能进行了测试与评价。[结果]石墨烯/多壁碳纳米管预分散浆的引入显著提升了涂层的耐盐雾性能。160°C固化时涂层的综合性能最优。在聚四氟乙烯乳液粒径为50 nm、添加量为1%~3%(质量分数)的条件下,涂层的耐盐雾时间长达1 344 h,动摩擦因数低至0.07。[结论]该低温固化水性无铬达克罗涂料具有良好的防腐与润滑功能,无需二次涂装,降低了能耗与污染,符合绿色制造要求,具有较广阔的应用前景。
Abstract:[Objective] To address the issues associated with traditional Dacromet coatings, including the carcinogenic risk of hexavalent chromium, high energy consumption due to high-temperature curing, relatively large friction coefficients, and the need for additional lubricating topcoats, a single-coat Dacromet coating with excellent corrosion resistance, low friction coefficient, and good environmental compatibility was developed. [Method] A in-house synthesized hydrolyzed silane prepolymer was used as the film-forming material, with flaky zinc and aluminum powders serving as anticorrosion pigments, and a pre-dispersed graphene/multi-walled carbon nanotube(MWCNT) slurry was incorporated. Furthermore, polytetrafluoroethylene(PTFE) emulsion was added by low-temperature curing technology. The comprehensive properties of the resulting coatings were tested and evaluated by systematically controlling the predispersion process parameters, curing temperature, as well as the particle size and dosage of the PTFE emulsion. [Result] The introduction of the pre-dispersed graphene/MWCNT slurry significantly enhanced the salt spray resistance of the coating. The optimal comprehensive performance of the coating was achieved when cured at 160°C. The coating prepared with 1%-30%(by mass) of PTFE emulsion with a particle size of 50 nm exhibited a neutral salt spray resistance up to 1 344 hours and a dynamic friction coefficient as low as 0.07. [Conclusion] The low-temperature curable, water-based, and chromium-free Dacromet coating possesses excellent anticorrosion and lubricating functions. It eliminates the need for secondary coating, reduces energy consumption and pollution, aligns with the requirement of green manufacturing, and demonstrates broad application prospects.
[1]王崇蕊,李杰庆,尹鸿鹍,等.无铬达克罗涂层技术的研究进展[J].当代化工研究, 2022(22):13-15.WANG C R, LI J Q, YIN H K, et al. Development of the chromiumfree Dacromet coating technology based on bibliometric[J]. Modern Chemical Research, 2022(22):13-15.
[2]魏小昕,冯立新,沈杰.无铬达克罗涂层的研究进展[J].现代涂料与涂装, 2014, 17(2):34-36, 41.WEI X X, FENG L X, SHEN J. Research progress of the non-chromium Dacromet technology coating[J]. Modern Paint&Finishing, 2014, 17(2):34-36, 41.
[3]宋积文,杜敏.无铬锌铝涂层发展现状[J].腐蚀与防护, 2007, 28(8):411-413.SONG J W, DU M. Current status of non-chromium Zn–Al coating[J].Corrosion&Protection, 2007, 28(8):411-413.
[4]林兵.国内达克罗技术的发展方向[J].电镀与精饰, 2003, 25(6):12-14.LIN B. Development direction of domestic Dacroment technique[J].Plating and Finishing, 2003, 25(6):12-14.
[5]赵晓莹.水性无铬达克罗涂料配方研究及其涂层性能测试[D].北京:北京化工大学, 2019.ZHAO X Y. Study on formulation of water-based chrome-free Dacromet coating and performance test of its coating[D]. Beijing:Beijing University of Chemical Technology, 2019.
[6]刘志梅,缪强,梁文萍,等.锌铝合金粉中Al含量对无铬达克罗涂层耐蚀性的影响[J].材料保护, 2015, 48(3):16-19.LIU Z M, MIAO Q, LIANG W P, et al. Effect of aluminum content in zinc–aluminum alloy powder on anticorrosion behavior of chromiumfree Dacromet coating[J]. Materials Protection, 2015, 48(3):16-19.
[7]南京工业大学.一种水性无铬达克罗涂液及其制备方法:201110236032.8[P]. 2011-12-14.ZHU C F, MAO B X. Water-based chrome-free Dacromet coating solution and preparation method thereof:CN102277022[P]. 2011–12–14.
[8]重庆航利实业有限责任公司.稀土溶胶改性复合锌铝低温烧结涂层浆料:201010223117.8[P]. 2010-11-10.ZHAO H, LI C L. Rare-earth sol modified composite zinc–aluminum lowtemperature sintered coating slurry:CN101880485[P]. 2010–11–10.
[9]SHEN Y L, WANG Y H, ZHAO C, et al. Ultra-low friction, ultra-fast response and low-VOC self-lubricating coating based on oil-filled silica microcapsules[J]. Tribology International, 2025, 209:110701.
[10]SAMYN P, VANHEUSDEN C, COSEMANS P. Performance of micronized biowax powders replacing PTFE fillers in bio-based epoxy resin coatings[J]. Coatings, 2025, 15(5):511.
[11]PANDEY K K, MAURYA S S, GRAIN A K, et al. Plasma-sprayed alumina coating reinforced with carbon nanotubes and graphene nanoplatelets:wear performance in adverse environment[J].Transactions of the Indian Institute of Metals, 2024, 77(8):2011-2022.
[12]徐黎黎,宋子键.水性超疏水复合涂料的制备及其机械稳定性[J].表面技术, 2018, 47(2):14-19.XU L L, SONG Z J. Preparation and mechanical stability of waterborne superhydrophobic composite paint[J]. Surface Technology, 2018, 47(2):14-19.
[13]VIGNESH R B, SETHURAMAN M G. Enhancement of corrosion protection of 3-glycidoxypropyltrimethoxysilane-based sol–gel coating through methylthiourea doping[J]. Journal of Coatings Technology and Research, 2014, 11(4):545-554.
[14]CALDARA M, COLLEONI C, GUIDO E, et al. Optical monitoring of sweat pH by a textile fabric wearable sensor based on covalently bonded litmus–3-glycidoxypropyltrimethoxysilane coating[J]. Sensors and Actuators B:Chemical, 2016, 222:213-220.
[15]李玉龙,耿文宝,熊佳,等.固化工艺对阻焊油墨结构及其在高温高湿环境中性能的影响[J].电镀与涂饰, 2025, 44(8):55-65.LI Y L, GENG W B, XIONG J, et al. Effect of curing process on structure of solder mask and its performance in high-temperature and high-humidity environment[J]. Electroplating&Finishing, 2025, 44(8):55-65.
基本信息:
DOI:10.19289/j.1004-227x.2026.02.009
中图分类号:TQ637
引用信息:
[1]王蝶,樊志彬,慈文斌,等.低摩擦因数低温固化水性达克罗涂料:性能与防腐蚀机制[J].电镀与涂饰,2026,45(02):72-81.DOI:10.19289/j.1004-227x.2026.02.009.
基金信息:
国网山东省电力公司科技项目“输变电工程钢制构件环保型防腐涂层技术研究及应用”(52062623003J)